[3,3-Bipyridine]-6,6-dicarboxaldehyde
CAS Number 1264748-06-2
Carbaldehyde Monomers, Chemistry Building Blocks, COF Ligands, Materials, MOF Ligands, Monomers, Porous Organic Frameworks
Covalent organic frameworks (COFs) bipyridine ligands
for synthesising COFs and their metal complexes for host-guest interactions
Specifications | MSDS | Literature and Reviews
[3,3-Bipyridine]-6,6-dicarboxaldehyde (CAS number 1264748-06-2), also known under IUPAC name of 3,3'-bipyridine-6,6'-dicarbaldehyde, is a derivative of 3,3’-bipyridine functionalised with two aldehyde groups. [3,3-Bipyridine]-6,6-dicarboxaldehyde undergoes reactions with amines to synthesise Schiff bases. The formation of the imine on the meso-carbon and the imine in the pyridine ring can coordinate to metal centre constructing a stable 5-membered ring. A metal-organic polyhedra composed of FeII and the Schiff base ligand prepared from [3,3-bipyridine]-6,6-dicarboxaldehyde and aniline, exhibits selective anion binding to PF6- over CF3SO3- and BF4-.
The metal-organic complexes from [3,3-bipyridine]-6,6-dicarboxaldehyde based COFs display a reversible binding affinity towards fluorescent dyes. This property enables the design of indicator-displacement assays.
Facile reactions
Aldehyde possesses excellent reactivity
High Purity
>98% Purity
Worldwide shipping
Quick and reliable shipping
MOF and COF ligands
Aldehyde ligand for cross-linked COF networks
General Information
CAS Number | 1264748-06-2 |
Chemical Formula | C12H8N2O2 |
Full Name | 3,3'-Bipyridine-6,6'-dicarbaldehyde |
Molecular Weight | 212.20 g/mol |
Synonyms | 5-(6-formyl-3-pyridyl)pyridine-2-carbaldehyde |
Classification / Family | Bipyridine ligands, Aldehydes, COFs, MOFs, Host-guest interactions |
Chemical Structure
Product Details
Purity | 98% |
Melting Point | N/A |
Appearance | Brown powder |
MSDS Documentation
[3,3-Bipyridine]-6,6-dicarboxaldehyde MSDS Sheet
Literature and Reviews
- Aqueous anion receptors through reduction of subcomponent self-assembled structures, J. Mosquera et al., Angew. Chem. Int. Ed., 53, 1556–1559 (2014); DOI: 10.1002/anie.201308117.
- Selective anion binding by a "Chameleon" capsule with a dynamically reconfigurable exterior, Y. Hristova et al., Chem. Sci., 2, 638 (2011); DOI: 10.1039/c0sc00495b.
- Dynamic imine chemistry in metal-organic polyhedra, H. Vardhan et al., RSC Adv., 5, 67011–67030 (2015); DOI: 10.1039/C5RA10801B.