B2PymPm

CAS Number 1266181-51-4

Charge Transport Layer Materials, Electron Transport Layer Materials, High Purity Sublimed Materials, Materials, OLED Materials, Semiconducting Molecules, TADF Materials

MSDS

B2PymPm, ETL and HBL material for OLED or photovoltaic devices

High-purity (>99.0%) and available online for priority dispatch

B2PymPm, 4,6-Bis(3,5-di(pyridin-2-yl)phenyl)-2-methylpyrimidine, has a 2-methylpyrimidine core with four pyridine pendants. It is used as an electron-transport layer or hole-blocking layer material for OLED or photovoltaic devices.

Pyridine rings enable intramolecular and intermolecular hydrogen bondings in and between the molecules. This can cause the molecules to become planar and enhance the horizontal molecular orientation, thus leading to high charge mobility.

General Information

CAS number	1266181-51-4
Full name	4,6-Bis(3,5-di(pyridin-2-yl)phenyl)-2-methylpyrimidine
Chemical formula	C₃₇H₂₆N₆
Molecular weight	554.64 g/mol
Absorption	λ_max 288 nm in chloroform
Fluorescence	λ_max 417 nm in chloroform
HOMO/LUMO	HOMO = 6.62 eV, LUMO = 3.55 eV [1]; E_T1 = 3.04 eV
Classification / Family	Pyrimidine derivatives, Light-emitting diodes, Organic electronics, Electron-transport layer (ETL) materials, Hole-blocking layer (HBL) materials, Sublimed materials.

Product Details

Purity	Sublimed: >99.0% (HPLC)
Melting point	Tm = 257 °C (melting point); Tg = 107 °C (glass transition temperature)
Appearance	White crystals/powder

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials.

Chemical Structure

Pricing

Grade	Order Code	Quantity	Price
Sublimed (>99% purity)	M2173A1	250 mg	£350
Sublimed (>99% purity)	M2173A1	500 mg	£580
Sublimed (>99% purity)	M2173A1	1 g	£900

MSDS Documentation

B2PymPm MSDS sheet

Literature and Reviews

Influence of Substituted Pyridine Rings on Physical Properties and Electron Mobilities of 2-Methylpyrimidine Skeleton-Based Electron Transporters, H, Sasabe et al., Adv. Funct. Mater., 21, 336–342 (2011); DOI: 10.1002/adfm.201001252.
Molecular Stacking Induced by Intermolecular C–H···N Hydrogen Bonds Leading to High Carrier Mobility in Vacuum-Deposited Organic Films, D. Yokoyama et al., Adv. Funct. Mater., 21, 1375–1382 (2011); DOI: 10.1002/adfm.201001919.
Development of high performance OLEDs for general lighting, H. Sasabe et al., J. Mater. Chem. C, 1, 1699 (2013); DOI: 10.1039/c2tc00584k.

Multifunctional Materials in High-Performance OLEDs: Challenges for Solid-State Lighting, H. Sasabe et al., Chem. Mater., 23, 621–630 (2011); DOI: 10.1021/cm1024052.
Recent Progress in Phosphorescent Organic Light-Emitting Devicee, H. Sasabe et al., Eur. J. Org. Chem., 7653–7663 (2013); DOI: 10.1002/ejoc.201300544.