9CAA

CAS Number 524-80-1

Electron / Hole Transport Layer Materials, Materials, Perovskite Interface Materials, Perovskite Materials, Self-Assembled Monolayers (SAMs), Semiconducting Molecules

MSDS

Small Self-Assembled Monolayer Molecule for High Efficiency Solar Cells

9CAA, Hole transport or extraction layer for NFA-polymer solar cells and p-i-n perovskite solar cells

9CAA (2-(9H-Carbazol-9-yl)acetic acid, CAS No. 524-80-1) consists of a carbazole function group with an acetic acid attached at 9-position. As a self-assembled monolayer material for photovoltaic solar cells, the carboxylic acid serves as the anchoring group to the electrode surface, methylene (-CH₂-) as the immediate relatively short spacer, and carbazole as the terminal.

Apart from phosphonic acid, carboxylic acid anchor has also been widely used in tin-lead (Sn-Pb) perovskite solar cells (PSCs) to form self-assembled monolayers to boost device performance and operational stability. In the case of Sn-Pb perovskite solar cells, the monolayer formed by the carboxylate anchoring group shows greater interaction on the interface and has a more favourable orientation and arrangement than the monolayer interface formed by phosphate anchoring group. It also leads to reduced nonradiative recombination and enhanced crystallinity in perovskite active materials by employing 9CAA as the self-assembled monolayer interface contact.

Based on 9CAA as the hole selective contact interface and narrow bandgap (~ 1.25 eV) Sn–Pb perovskite active layer, PSCs demonstrated efficiencies of up to 23.1% with an open-circuit voltage of up to 0.89 V. Moreover, 93% of their initial efficiency was retained for the unencapsulated devices after storage in N₂ atmosphere for over 2500 h.

Serving as hole selective contact for organic solar cells and perovskite solar cells, 9CAA is an alternative to PEDOT:PSS with superior performance with the convenience of solution deposition at low concentration, i.e. 1 mM.

Solution Processing Procedure

Typical processing solvents: Ethanol, methanol, IPA, DMF, THF
Typical concentration: 1 mM - 1.0 mg/ml
Typical processing procedure:

9CAA is dissolved in ethanol with a concentration of 0.3 mg/mL. The 9CAA solution is spin-coated on FTO for 30 s at the speed of 3000 rpm, and then annealed for 10 min at 100 ℃ (DOI 10.1002/adma.202312264).

General Information

CAS Number	524-80-1
Chemical Formula	C₁₄H₁₁NO₂
Molecular Weight	225.24 g/mol
Absorption*	λ_max (n.a.)
Fluorescence	λ_em (n.a.)
HOMO/LUMO	5.35 eV (WF FTO)
Synonyms	Carbazol-9-yl-acetic acid, 2-(9H-Carbazol-9-yl)acetic acid, CzAA
Classification or Family	Carbazole derivatives, Self-assembly Monolayers, Hole transport layer, Hole extraction layer, p-i-n Perovskite solar cells, Organic photovoltaics

Product Details

Purity	> 98% (HPLC)
Melting Point	191-194 °C
Appearance	White powder/crystals

Chemical Structure

MSDS Documentation

9CAA MSDS Sheet

Literature and Reviews

Z. Zhang et al. (2024); Anchoring Charge Selective Self-Assembled Monolayers for Tin–Lead Perovskite Solar Cells, Adv. Mater., 36 (18), 2312264; DOI: 10.1002/adma.202312264.