DMAC-BPP

CAS Number 1836192-40-5

Dopant Materials, High Purity Sublimed Materials, Host Materials, Materials, OLED Materials, Semiconducting Molecules, TADF Materials

MSDS

DMAC-BPP, efficient TADF bluish-green emitter

High-purity (>99.0%) and available online for priority dispatch

DMAC-BPP, namely 10,10′‐[5‐(6‐[1,1′‐biphenyl]‐4‐yl‐2‐phenyl‐4‐pyrimidinyl)‐1,3‐phenylene]bis[9,10‐dihydro‐9,9‐dimethyl‐acridine], has a structure containing two acridines units bridged by a phenyl with a phenylbiphenylpyrimidine, each at the meta positions.

DMAC-BPP is an efficient TADF bluish-green emitter which can also be used as yellow and red phosphorescent host material for TADF-OLED devices.

General Information

CAS number	1836192-40-5
Full name	10,10′‐[5‐(6‐[1,1′‐biphenyl]‐4‐yl‐2‐phenyl‐4‐pyrimidinyl)‐1,3‐phenylene]bis[9,10‐dihydro‐9,9‐dimethyl‐acridine]
Chemical formula	C₅₈H₄₆N₄
Molecular weight	788.01 g/mol
Absorption	λ_max 282 nm
Fluorescence	λ_em 496 nm
HOMO/LUMO	HOMO = 5.38 eV, LUMO = 2.46 eV [1]
Synonyms	BPP-DMAC, Acridine, 10,10'-[5-(6-[1,1'-biphenyl]-4-yl-2-phenyl-4-pyrimidinyl)-1,3-phenylene]bis[9,10-dihydro-9,9-dimethyl-]
Classification / Family	Acridines, TADF bluish green emitter materials, Phosphorescent organic light-emitting devices (PHOLEDs), Sublimed materials

Product Details

Purity	Sublimed >99.0% (HPLC)
Melting point	T_g = 220 °C (lit.)
Appearance	Light yellow powder/crystals

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials.

Chemical Structure

Pricing

Grade	Order Code	Quantity	Price
Sublimed (>99.0% purity)	M2247A1	100 mg	£300
Sublimed (>99.0% purity)	M2247A1	250 mg	£600
Sublimed (>99.0% purity)	M2247A1	500 mg	£1000
Sublimed (>99.0% purity)	M2247A1	1 g	£1750

MSDS Documentation

DMAC-BPP MSDS sheet

Literature and Reviews

Stable and efficient phosphorescent organic light-emitting device utilizing δ-carboline-containing thermally activated delayed fluorescence host, H. Wang et al., J. Mater. Chem. C, 2020,8, 3800-3806 (2020); DOI: 10.1039/C9TC06601B.
Efficiency enhancement in an inverted organic light-emitting device with a TiO2 electron injection layer through interfacial engineering, C. Zang et al., . Mater. Chem. C, 8, 8206-8212 (2020); doi: 10.1039/D0TC01040E.
Bluish‐Green Thermally Activated Delayed Fluorescence Material for Blue‐Hazard Free Hybrid White Organic Light‐Emitting Device with High Color Quality and Low Efficiency Roll‐Off, H. Wang et al., Adv. Opt. Mater, 7 (9), 801718 (2019); DOI: 10.1002/adom.201801718.

An efficient and stable hybrid organic light-emitting device based on an inorganic metal oxide hole transport layer and an electron transport layer, J. Zhang et al., J. Mater. Chem. C, 7, 1991-1998 (2019); doi: 10.1039/C8TC06135A.