[1,1'3',1''-Terphenyl]-4,4'',5'-tricarbaldehyde
CAS Number 1977585-07-1
Carbaldehyde Monomers, Chemistry Building Blocks, COF Ligands, Monomers, Non-Heterocyclic Building Blocks, Porous Organic Frameworks![[1,1'3',1''-Terphenyl]-4,4'',5'-tricarbaldehyde MSDS](http://www.ossila.com/cdn/shop/t/305/assets/product-downloads-msds.svg?v=110835251789389989421733214861){kind=small}
![[1,1'3',1''-Terphenyl]-4,4'',5'-tricarbaldehyde CAS 1977585-07-1](http://www.ossila.com/cdn/shop/files/1-13-1-terphenyl-4-4-5-tricarbaldehyde-structure-title.png?v=1722522878)
Covalent Organic Frameworks (COFs) Terphenyl Ligand
Functionalized with three aldehydes for heteroporous COFs
Overview | Product Information | MSDS | Related Products
[1,1'3',1''-Terphenyl]-4,4'',5'-tricarbaldehyde (CAS number 1977585-07-1) is a m-terphenyl ligand bearing three aldehyde groups. [1,1'3',1''-Terphenyl]-4,4'',5'-tricarbaldehyde belongs the C2v point group, which can form 2D heteropore COFs. The resulting 2D heteroporous COFs display two kinds of hexagonal micropores with different shapes and sizes.
The aldehyde groups in [1,1':3',1''-terphenyl]-4,4'',5'-tricarbaldehyde participate in multiple reactions, such as aldol condensation, amination reaction, Knoevenagel reaction, and Wittig reaction, for the synthesis of COFs with a wide variety of linkers.
MOF and COF Ligands
m-terphenyl ligand for cross-linked COF/MOF networks
Facile Reactions
Aldehyde possesses excellent reactivity
High Purity
> 98% pure
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General Information
| CAS Number | 1977585-07-1 |
|---|---|
| Chemical Formula | C21H14O3 |
| Full Name | 1,1':3',1''-Terphenyl-4,4'',5'-tricarbaldehyde |
| Molecular Weight | 314.34 g/mol |
| Synonyms | 5-(4-Formylphenyl)-[1,1'-biphenyl]-3,4'-dicarbaldehyde, TPTA |
| Classification or Family | Porous organic frameworks, COFs, Terphenyl building blocks, Carbaldehydes |
Chemical Structure
![[1,1'3',1''-Terphenyl]-4,4'',5'-tricarbaldehyde chemical structure, CAS 1977585-07-1](https://www.ossila.com/cdn/shop/files/1-13-1-terphenyl-4-4-5-tricarbaldehyde-structure-body.png)
Product Details
| Purity | > 98% |
|---|---|
| Melting Point | N/A |
| Appearance | Dark beige powder |
MSDS Documentation
![[1,1'3',1''-Terphenyl]-4,4'',5'-tricarbaldehyde MSDS Sheet](https://www.ossila.com/cdn/shop/files/product-downloads-msds.svg){kind=small}
[1,1'3',1''-Terphenyl]-4,4'',5'-tricarbaldehyde MSDS Sheet
References
- Heteropore covalent organic frameworks: a new class of porous organic polymers with well-ordered hierarchical porosities, R.-R. Liang et al., Org. Chem. Front., 5, 3341–3356 (2018); DOI: 10.1039/C8QO00830B.
- Rational design, structure properties, and synthesis strategies of dual-pore covalent organic frameworks (COFs) for potent applications: A review, S. Patial et al., Environ. Res., 218, 114982 (2023); DOI: 10.1016/j.envres.2022.114982.
- Effects of connecting sequences of building blocks on reticular synthesis of covalent organic frameworks, D.-L. Ma et al., Nano Res., 14, 381–386 (2021); DOI: 10.1007/s12274-020-2723-y.
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