1,3,5-Tris(4-hydroxyphenyl)benzene
CAS Number 15797-52-1
Chemistry Building Blocks, COF Ligands, Monomers, Non-Heterocyclic Building Blocks, Porous Organic Frameworks
Covalent Organic Frameworks (COFs) Triphenylbenzene Ligand
for the synthesis of ester-linked COFs, hydrogen-bonded organic frameworks, and light emitting macromolecules
Overview | Product Information | Related Products
1,3,5-Tris(4-hydroxyphenyl)benzene (CAS number 15797-52-1) is a triphenylbenzene building block with three hydroxyl substituents. 1,3,5-Tris(4-hydroxyphenyl)benzene is used in the synthesis of ester linkage COFs with di(pyridin-2-yl) terephthalate. Such ester-linked COFs exhibit hcb topology with a surface area up to 2092 m2/g.
1,3,5-Tris(4-hydroxyphenyl)benzene is also applied for the fabrication of hydrogen-bonded organic frameworks through a bottom-up procedure. Density functional theory (DFT) study reveals that the constituting molecules with a planar conformation are linked to each other via H-O hydrogen bonding between hydroxyl groups.
1,3,5-Tris(4-hydroxyphenyl)benzene also finds its application in the synthesis of triphenylbenzene-based carbazoles, photoluminescent macromolecules. The resulting macromolecules exhibit two intense bands at 353 and 369 nm, which can be potentially used in OLEDs.
MOF and COF ligands
Triphenylbenzene ligand for cross-linked COF/MOF networks
Facile reactions
Hydroxyl groups possesses excellent reactivity
High purity
> 98% pure
Worldwide shipping
Quick and reliable shipping
General Information
| CAS Number | 15797-52-1 |
|---|---|
| Chemical Formula | C24H18O3 |
| Full Name | 4-[3,5-bis(4-hydroxyphenyl)phenyl]phenol |
| Molecular Weight | 354.4 g/mol |
| Synonyms | 5'-(4-Hydroxyphenyl)-[1,1':3',1''-terphenyl]-4,4''-diol, THPB, Btp |
| Classification or Family | Porous organic frameworks, COFs, Triphenylbenzenes, Hydrogen-bonded organic frameworks, Photoluminescence |
Chemical Structure
Product Details
| Purity | > 98% |
|---|---|
| Melting Point | N/A |
| Appearance | Beige powder |
MSDS Documentation
1,3,5-Tris(4-hydroxyphenyl)benzene MSDS Sheet
References
- 1,3,5-Triphenylbenzene: a versatile photoluminescent chemo-sensor platform and supramolecular building block, P. Vishnoi et al., RSC Adv., 8, 17535 (2018); DOI: 10.1039/c8ra02658k.
- Blue emitting star-shaped and octasilsesquioxane-based polyanions bearing boron clusters. Photophysical and thermal properties, J. Cabrera-González et al., Molecules, 25, 1210 (2020), DOI: 10.3390/molecules25051210.
- Large-scale 2D heterostructures from hydrogen-bonded organic frameworks and graphene with distinct Dirac and flat bands, X. Zhang et al., Nat. Commun., 15, 5934 (2024); DOI: 10.1038/s41467-024-50211-5.
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