2,5-Dibutoxyterephthalohydrazide
CAS Number 1136292-72-2
Chemistry Building Blocks, COF Ligands, Monomers, Porous Organic Frameworks
Covalent Organic Frameworks (COFs) dibutoxybenzene ligand
for the synthesis of COFs in application of capturing pollution and biobutanol separation
Overview | Product Information | Related Products
2,5-Dibutoxyterephthalohydrazide (CAS number 1136292-72-2) is a dibutoxybenzene building block bearing two para-substituted hydrazide groups. The hydrazide functional groups readily react with aldehyde derivatives for the synthesis of hydrazone-linkage COFs. The resulting COFs are developed for selective uranium extraction with an uptake capacity of 11.3 mg/g in seawater. Mechanistic study reveals that the alkoxy groups enhance the binding of [UO2]2+ at the hydrazone sites through hydrogen bonding.
COFs prepared from 2,5-dibutoxyterephthalohydrazide are also used for capturing iodine pollutants with a high capacity of 2.16 g/g (I2) in air and 4.46 g/g (I3-) in aqueous solution.
MOF and COF ligands
Dibutoxybenzene ligand for cross-linked COF/MOF networks
Facile reactions
Hydrazide possesses excellent reactivity
High purity
> 97% pure
Worldwide shipping
Quick and reliable shipping
General Information
| CAS Number | 1136292-72-2 |
|---|---|
| Chemical Formula | C16H26N4O4 |
| Full Name | 2,5-Dibutoxyterephthalohydrazide |
| Molecular Weight | 338.40 g/mol |
| Synonyms | 2,5-Dibutoxybenzene-1,4-dicarbohydrazide |
| Classification or Family | Porous organic frameworks, COFs, Hydrazide, Water purification, Biofuel |
Chemical Structure
Product Details
| Purity | > 97% |
|---|---|
| Melting Point | N/A |
| Appearance | Off-white powder |
MSDS Documentation
2,5-Dibutoxyterephthalohydrazide MSDS Sheet
References
- Ultra-high selectivity COF-based membranes for biobutanol production, H. Fan et al., J. Mater. Chem. A, 6, 17602–17611 (2018); DOI: 10.1039/C8TA06902F.
- Rational design of cooperative chelating sites on covalent organic frameworks for highly selective uranium extraction from seawater, Y. Xie et al., Cell Rep. Phys. Sci., 4 (1), 101220 (2023); DOI: 10.1016/j.xcrp.2022.101220.
- Engineering the pore environment of antiparallel stacked covalent organic frameworks for capture of iodine pollutants, Y. Xie et al., Nat. Commun., 15, 2671 (2024); DOI: 10.1038/s41467-024-46942-0.
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