2,5-Dimethoxyterephthalohydrazide
CAS Number 114503-42-3
Chemistry Building Blocks, COF Ligands, Materials, Monomers, Porous Organic Frameworks
Covalent Organic Frameworks (COFs) Dimethoxybenzene Ligand
for hydrazone linkage COFs in applications of photocatalytic hydrogen evolution and pH sensors
Overview | Product Information | Related Products
2,5-Dimethoxyterephthalohydrazide (CAS number 114503-42-3) is a p-dimethoxybenzene functionalized with two hydrazide groups at para-position. 2,5-Dimethoxyterephthalohydrazide reacts with aldehydes for the synthesis of COFs with hydrazone linkage. A heterogeneous COF photocatalyst is synthesized from 2,5-dimethoxyterephthalohydrazide and triformylbenzene. The COF displays surface area of 1501 m2/g as well as efficient photocatalytic activity towards cross-dehydrogenative coupling reactions.
2,5-Dimethoxyterephthalohydrazide is also used to prepare β-ketoenamine based COFs. The resulting 2D COF exhibits high crystallinity, good stability, and photoluminescence properties. Additionally, the fluorescent emission varies corresponding to the pH value in aqueous solutions.
Dimethoxybenzene building block
hydrazide ligand for cross-linked COF networks
Facile reactions
hydrazide possesses excellent reactivity
High purity
>97% pure
Worldwide shipping
Quick and reliable shipping
General Information
| CAS Number | 114503-42-3 |
|---|---|
| Chemical Formula | C10H14N4O4 |
| Full Name | 2,5-Dimethoxyterephthalohydrazide |
| Molecular Weight | 254.25 g/mol |
| Synonyms | 2,5-Dimethoxybenzene-1,4-dicarbohydrazide, DMTH |
| Classification or Family | Porous organic frameworks, Hydrazide building blocks, Photocatalysts, Hydrogen evolution |
Chemical Structure
Product Details
| Purity | > 97% |
|---|---|
| Melting Point | N/A |
| Appearance | Off-white powder |
MSDS Documentation
2,5-Dimethoxyterephthalohydrazide MSDS Sheet
References
- Covalent organic frameworks as pH responsive signalling scaffolds, Y. Zhang et al., Chem. Commun., 52, 11088 (2016); DOI: 10.1039/c6cc05748a.
- Recent advances in the use of covalent organic frameworks as heterogenous photocatalysts in organic synthesis, A. López-Magano, Adv. Mater., 35, 2209475 (2023); DOI: 10.1002/adma.202209475.
- A hydrazone-based covalent organic framework as an efficient and reusable photocatalyst for the cross-dehydrogenative coupling reaction of N-aryltetrahydroisoquinolines, W. Liu et al., ChemSusChem., 10 (4), 664&nash;669 (2016); DOI: 10.1002/cssc.201601702.
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