2,5-Dipropoxyterephthalohydrazide
CAS Number 2143456-42-0
Chemistry Building Blocks, COF Ligands, Materials, Monomers, Porous Organic Frameworks
Covalent Organic Frameworks (COFs) Dipropoxybenzene Ligand
capped with hydrazide functional groups for the synthesis of COFs in application of batteries and supercapacitors
Overview | Product Information | Related Products
2,5-Dipropoxyterephthalohydrazide (CAS number 2143456-42-0) is a dipropoxybenzene building block capped with two hydrazides at the para-position. 2,5-Dipropoxyterephthalohydrazide is commonly used to synthesize hydrazone linkage COFs such as COF-42 (with triformylbenzene) and COF-43 (with triformylphenylbenzene).
2,5-Dipropoxyterephthalohydrazide reacts with 2,4,6-triformylphloroglucinol for the synthesis of β-keto-enamine 2D-COFs. β-Keto-enamine 2D-COFs are formed after an irreversible tautomerisation from their enol form to the keto form. Such COFs are explored in combination with ruthenium (Ru) nanoparticle decorated carbon nanotubes for a highly efficient cathode in Li-CO2 batteries. The COF-based Li-CO2 exhibits a capacity of 27348 mAh/g at a current density of 200 mA/g.
MOF and COF ligands
Dipropoxybenzene ligand for cross-linked COF/MOF networks
Facile reactions
Hydrazide possesses excellent reactivity
High purity
>98% pure
Worldwide shipping
Quick and reliable shipping
General Information
| CAS Number | 2143456-42-0 |
|---|---|
| Chemical Formula | C14H22N4O4 |
| Full Name | 2,5-Dipropoxyterephthalohydrazide |
| Molecular Weight | 310.35 g/mol |
| Synonyms | 2,5-Dipropoxybenzene-1,4-dicarbohydrazide |
| Classification or Family | Porous organic frameworks, COFs, Hydrazides, Batteries, Supercapacitors |
Chemical Structure
Product Details
| Purity | > 98% |
|---|---|
| Melting Point | N/A |
| Appearance | Off-white to pale yellow fluffy powder |
MSDS Documentation
2,5-Dipropoxyterephthalohydrazide MSDS Sheet
References
- Covalent-organic-framework-based Li&ndashCO2 batteries, X. Li et al., Adv. Mater., 31 (48), 1905879 (2019); DOI: 10.1002/adma.201905879.
- Facile synthesis of –C=N– linked covalent organic frameworks under ambient conditions, S.-Y. Ding et al., : Chem. Commun., 53, 11956 (2017); DOI: 10.1039/c7cc05779b.
- 2D covalent-organic framework electrodes for supercapacitors and rechargeable metal-ion batteries, S. Kandambeth et al., Adv. Energy Mater., 12, 2100177 (2022); DOI: 10.1002/aenm.202100177.
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