3N-T2T
CAS Number 939430-26-9
High Purity Sublimed Materials, Host Materials, Materials, Semiconducting Molecules, TADF Materials
3N-T2T, a versatile transport layer material
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3N-T2T is a family member of star-shaped 1,3,5-triazine-based electron transport host materials. Further introduction of peripheral pyridyl groups to the triazole core enhances the electron transport/injection properties.
Due to its electron-deficient nature, 3N-T2T can also be used as an electron acceptor, with electron donors such as tris-PCz and DSDTAF to form green exciplexes either as light-emitting active layer or co-host materials.
With a similar chemical structure to TmPyPB, which has a star-shaped 1,3,5-triphenylbenzene core instead, 3N-T2T has a deeper HOMO energy level which could be used as hole blocking layer material.
General Information
| CAS number | 939430-26-9 |
|---|---|
| Chemical formula | C36H24N6 |
| Molecular weight | 540.63 g/mol |
| Absorption | λmax 275 nm |
| Fluorescence | λem 357, 375 nm |
| HOMO/LUMO | HOMO = 6.77 eV, LUMO = 2.7 eV [1] |
| Chemical name | 2,4,6-Tris(3-(3-pyridyl)phenyl)-1,3,5-triazine |
| Synonyms | TmPyTz, TmPPyTz |
| Classification / Family | Triazine derivatives, TADF exciplex host materials, Phosphorescent host materials, Sublimed materials |
Product Details
| Purity | Sublimed >99.0% (HPLC) |
|---|---|
| Melting point | TGA: >300 °C (0.5% weight loss) |
| Appearance | Off-white powder/crystals |
*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the sublimed materials.
Chemical Structure
Pricing
| Grade | Order Code | Quantity | Price |
|---|---|---|---|
| Sublimed (>99.0% purity) | M2275A1 | 100 mg | £230 |
| Sublimed (>99.0% purity) | M2275A1 | 250 mg | £460 |
| Sublimed (>99.0% purity) | M2275A1 | 500 mg | £800 |
| Sublimed (>99.0% purity) | M2275A1 | 1 g | £1450 |
MSDS Documentation
3N-T2T MSDS sheetLiterature and Reviews
- New naphthyridine-based bipolar host materials for thermally activated delayed fluorescent organic light-emitting diodes, T-C. Yeh et al., Org. Electronics, 70, 55-62 (2019); DOI: 10.1016/j.orgel.2019.04.003.
- Peripheral Modification of 1,3,5-Triazine Based Electron-Transporting Host Materials for Blue, Green, Yellow, Red, and White Electrophosphorescent Devices, H-F. Chen et al., J. Mater. Chem., 22, 15620-15627 (2012); DOI: 10.1039/C2JM31904G.
- Remote Steric Effect as a Facile Strategy for Improving the Efficiency of Exciplex-Based OLEDs, W-Y. Hung et al., ACS Appl. Mater. Interfaces, 9, 8, 7355–7361 (2017); DOI: 10.1021/acsami.6b16083.