FREE shipping to on qualifying orders when you spend or more, processed by Ossila BV. All prices ex. VAT. Qualifying orders ship free worldwide! Fast, secure, and backed by the Ossila guarantee. It looks like you are visiting from , click to shop in or change country. Orders to the EU are processed by our EU office.
Join the Team About Ossila Contact Us | How to Order Shipping |Log In Create Account| Worldwide, $ USD   Flag

It looks like you are using an unsupported browser. You can still place orders by emailing us on info@ossila.com, but you may experience issues browsing our website. Please consider upgrading to a modern browser for better security and an improved browsing experience.

AQ(PhDPA)<sub>2</sub> CAS 1640978-33-1
Product Code M2387A1-100mg
Price $540 ex. VAT
$ USD

How to Order | Shipping

AQ(PhDPA)2 red dopant material

Available in high purity, sublimed grade for highly efficient TADF-OLED, energy storage and waveguide applications.

AQ(PhDPA)2, 2,6-bis[4-(diphenylamino)phenyl]-9,10-Anthracenedione, has a molecular structure of the D-π-A-π-D-type chromophore with two electron-rich triphenylamine units attached to an electron deficient anthraquinone centre at 2,6-positions. AQ(PhDPA)2 has been used as an efficient red TADF emitter.

Mono-polymer PBDAPA, prepared from AQ(PhDPA)2 as the monomer, shows unique urchin-like morphology with an improved specific surface area of ∼129.6 m2 g-1. PBDAPA presents double charge-discharge characteristics with specific capacity of 132.7 mAh g-1. Also, by using the vertical top pumping mode of a 450 nm LED, passive SU-8 waveguide with AQ(PhDPA)2 doped PMMA as the upper cladding presented a gain of 2.6 dB cm-1.

General Information

CAS Number 1640978-33-1
Chemical Formula C50H34N2O2
Molecular Weight 694.82 g/mol
Absorption λmax 614 nm in toluene [1]
Fluorescence λmax 304 nm, 335 nm, 367 nm and 455 nm in toluene
HOMO/LUMO HOMO = 5.90 eV, LUMO = 3.60 eV [1]
Full Name 2,6-bis[4-(diphenylamino)phenyl]-9,10-Anthracenedione
Synonyms AQ-b1, BDAPA
Classification / Family Triphenylamine derivatives, Anthracenedione, TADF Red dopant, Sublimed materials

Chemical Structure

AQ(PhDPA)2 chemical structure, 2,6-bis[4-(diphenylamino)phenyl]-9,10-Anthracenedione, 1640978-33-1
Chemical Structure of 2,6-bis[4-(diphenylamino)phenyl]-9,10-Anthracenedione, AQ(PhDPA)2, CAS 1640978-33-1

Product Details

Purity Sublimed* >99.0% (HPLC)
Melting Point N/A
Appearance Red powder/crystals

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials.

MSDS Documentation

AQ(PhDPA)2 MSDSAQ(PhDPA)2 MSDS sheet

Pricing

Grade Order Code Quantity Price
Sublimed (>99.0% purity) M2387A1 100 mg £400
Sublimed (>99.0% purity) M2387A1 250 mg £800
Sublimed (>99.0% purity) M2387A1 500 mg £1350
Sublimed (>99.0% purity) M2387A1 1 g £2300

Literature and Reviews

  1. Solution-processed multiple exciplexes via spirofluorene and S-triazine moieties for red thermally activated delayed fluorescence emissive layer OLEDs, Org. Electron., 96, 106181 (2021); DOI: 10.1016/j.orgel.2021.106184.
  2. Optical Gain at 637 nm Wavelength in Polymer Waveguide Amplifier Under Commercial LED Pumping for Planar Photonic Integration, C. Wang et al., Adv. Opt. Mater., 10 (13), 2200205 (2022); DOI: 10.1002/adom.202200205.
  3. A Novel Anthraquinone-Containing Poly(Triphenylamine) Derivative: Preparation and Electrochemical Performance as Cathode for Lithium-Ion Batteries, C. Su et al., ChemElectroChem, 7 (19), 4101-4107 (2020); DOI: 10.1002/celc.202001084.

Return to the top