DMAC-TRZ

CAS Number 1628752-98-6

Dopant Materials, High Purity Sublimed Materials, Materials, Semiconducting Molecules, TADF Materials

DMAC-TRZ, sky blue TADF emitter for highly efficient doped and non-doped OLED devices

High purity (>99.0%) and high PLQY in doped and neat films

DMAC-TRZ, 10-(4-(4,6-Diphenyl-1,3,5-triazin-2-yl)phenyl)-9,9-dimethyl-9,10-dihydroacridine, has a bipolar structure containing both 2,4,6-triphenyl-1,3,5-triazine (TRZ) as the electron-accepting and 9,9-dimethyl-9,10-dihydroacridine (DMAC) as the electron-donating moieties.

DMAC-TRZ is a well-known sky blue TADF emitter for both highly efficient doped and non-doped OLED devices, with high maximum external quantum efficiencies (EQE) over 20%. It shows not only high photoluminescence quantum yield (PLQY, ≥90%) in doped films but also high PLQY (83%) in neat films with low concentration quenching.

General Information

CAS number	1628752-98-6
Full name	10-(4-(4,6-Diphenyl-1,3,5-triazin-2-yl)phenyl)-9,9-dimethyl-9,10-dihydroacridine
Chemical formula	C₃₆H₂₈N₄
Molecular weight	516.63 g/mol
Absorption	λ_max 390 nm in Toluene
PL	λ_em 425 nm in Toluene
HOMO/LUMO	HOMO = 5.92 eV, LUMO = 2.92 eV; T₁=2.91 eV[1]
Synonyms
Classification / Family	Acridine derivatives, Sky-blue TADF emitter, Phosphorescent organic light-emitting devices (PHOLEDs), Sublimed materials

Product Details

Purity	Sublimed >99.0% (HPLC)
Melting point	m_p = 234 °C (DSC), T_g = 91 °C
Appearance	Pale yellow powder/crystals

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials.

Chemical Structure

Device Structure(s)

Device structure	ITO anode/PEDOT:PSS (70 nm)/TAPC (15 nm)/mCP (5nm)/mCPCN:DMAC-TRZ 8 wt.% (20 nm)/DPPS (5 nm)/3TPYMB (45 nm)/LiF (0.5 nm)/Al (150 nm) [1]
Colour	Greenish-Blue
Max Current Efficiency	66.8 cd/A
Max. Power Efficiency	65.6 Im/W
Max. EQE	26.5%

Device structure	ITO anode/PEDOT:PSS (70 nm)/TAPC (15 nm)/mCP (5nm)/DMAC-TRZ (20 nm)/DPPS (5 nm)/3TPYMB (45 nm)/LiF (0.5 nm)/Al (150 nm) [1]
Colour	Greenish-Blue
Max Current Efficiency	61.6 cd/A
Max. Power Efficiency	45.7 Im/W
Max. EQE	20.0%

Device structure	ITO/PEDOT:PSS/X-OTPD* (20 nm)]/DCzPPy:20 wt% DMAC-TRZ (35 nm)/TmPyPB (55 nm)/CsF (1.5 nm)/Al [2]
Colour	Greenish-Blue
Max Current Efficiency	30.4 cd/A
Max. Power Efficiency	24.5 Im/W
Max. EQE	8.8%

Device structure	ITO/PEDOT:PSS/X-QUPD (10 nm)/X-DCDPA* (10 nm)/DCzPPy:20 wt% DMAC-TRZ (35 nm)/TmPyPB (55 nm)/CsF (1.5 nm)/Al [2]
Colour	Greenish-Blue
Max Current Efficiency	79.6 cd/A
Max. Power Efficiency	48.6 Im/W
Max. EQE	25.9%

*For chemical structure information, please refer to the cited references.

Pricing

Grade	Order Code	Quantity	Price
Sublimed (>99.0% purity)	M2343A1	100 mg	£240
Sublimed (>99.0% purity)	M2343A1	250 mg	£480
Sublimed (>99.0% purity)	M2343A1	500 mg	£760
Sublimed (>99.0% purity)	M2343A1	1 g	£1250

MSDS Documentation

DMAC-TRZ MSDS sheet

Literature and Reviews

Versatile Thermally Activated Delayed Fluorescence Emitter for Both Highly Efficient Doped and Non‐Doped Organic Light Emitting Devices, W. Tsai et al., Chem. Commun., 51, 13662-13665 (2015); DOI: 10.1039/C5CC05022G.
Solution-Processed Thermally Activated Delayed Fluorescent OLED with High EQE as 31% Using High Triplet Energy Crosslinkable Hole Transport Materials, K. Tsai et al., Adv. Funct. Mater., 29 (15), 1901025 (2019); DOI: 10.1002/adfm.201901025.
Highly Efficient Organic Light Emitting Diode with 37% External Quantum Efficiency Using Thermally Activated Delayed Fluorescence from Spiroacridine-Triazine Hybrid Emitter Simultaneously Having Unitary Photoluminescence and Strongly Horizontal Emitting Dipoles, T. Lin et al., Adv. Mater., 28 (32), 6976-6983 (2016); DOI: 10.1002/adma.201601675.