DTS(FBTTh₂)₂

CAS Number 1402460-84-7

Materials, Organic Conductors, Semiconducting Molecules, Small Molecule OPV Donors

DTS(FBTTh<sub>2</sub>)<sub>2</sub> CAS 1402460-84-7

A D-A-D type of low band-gap, small-molecule donor, DTS(FBTTh₂)₂, CAS number 1402460-84-7, is a semiconducting material for solution-processed bulk heterojunction (BHJ) highly-efficient solar cells.

Studies have shown that the addition of DIO (diiodooctane) to the donor/acceptor blend or thermal annealing treatment can significantly enhance the crystallinity of the device film, thus enabling higher device performances to be achieved [2].

High purity

>98% pure DTS(FBTTh₂)₂

Worldwide shipping

Quick and reliable shipping

D-A-D low band-gap

For solution-processed bulk heterojunction (BHJ) highly-efficient solar cells

Tuneable crystallinity

enabling higher device performances

General Information

Full name	7,7′-[4,4-Bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b′]dithiophene-2,6-diyl]bis[6-fluoro-4-(5′-hexyl-[2,2′-bithiophen]-5-yl)benzo[c][1,2,5]thiadiazole]
Purity	>98.0% (by 1H NMR)
Synonyms	F-DTS, p-DTS(FBTTh₂)₂
Chemical formula	C₆₄H₇₂F₂N₄S₈Si
Molecular weight	1219.89 g/mol
CAS number	1402460-84-7
HOMO / LUMO	HOMO = -5.12 eV LUMO = -3.34 eV [1]
Solubility/processing solvents	Chloroform, chlorobenzene
Classification / Family	Heterocyclic five-membered ring, Organic semiconducting materials, Organic photovoltaics, Small molecule donor, SM-OPVs

Chemical Structure

MSDS Documentation

DTS(FBTTh2)2 MSDS sheet

Pricing

Batch	Quantity	Price
M2085A1	100 mg	£360
M2085A1	250 mg	£800
M2085A1	500 mg	£1450
M2085A1	1 g	£2600
M2085A1	5 - 10 g*	Please enquire

*For order quantities of 5-10 grams, the lead time is 4-6 weeks.

Literature and Reviews

Non-Basic High-Performance Molecules for Solution-Processed Organic Solar Cells, T. S. van der Poll et al., Adv. Mater., 24(17), 3646–3649 (2012); DOI: 10.1002/adma.201201127.
Film Morphology of High Efficiency Solution-Processed Small-Molecule Solar Cells, J. A. Love et al, Adv. Funct. Mater., 23, 5019–502 (2013), DOI: 10.1002/adfm.201300099.
Highly thermally stable non-fullerene organic solar cells: p-DTS(FBTTh2)2:P(NDI2OD-T2) bulk heterojunction, Y. Kim et al., Nano Energy, 15, 343-352 (2015); https://doi.org/10.1016/j.nanoen.2015.04.035.

Single Crystal Microwires of p-DTS(FBTTh2)2 and Their Use in the Fabrication of Field-Effect Transistors and Photodetectors, Q. Cui et al., ADv. Funct. Mater., 28(4), 1702073 (2018); DOI: 10.1002/adfm.201702073.
A High-Performing Solution-Processed Small Molecule:Perylene Diimide Bulk Heterojunction Solar Cell, A. Sharenk et al., Adv. Mater., 25 (32), 4403–4406 (2013); DOI: 10.1002/adma.201301167.