IDTB6-2Sn

CAS Number 1252555-61-5

Chemistry Building Blocks, Heterocyclic Building Blocks, Materials, Monomers, Organotin Compounds

IDTB6-2Sn, high purity monomer

An intermediate in polymer organic solar cells for low band gap polymers and NFAs

Specifications | MSDS | Literature and Reviews

4,4,9,9-tetrakis(4-hexylphenyl)-4,9-dihydro-s-indaceno[1,2-b:5,6-b']dithiophene-2,7-diyl)bis(trimethylstannane) (IDTB6-2Sn), CAS number 1252555-61-5, has a structure of four hexylphenyl groups attached to an indaceno[1,2-b:5,6-b']dithiophene (IDT) core. IDTB6-2Sn has trimethylstannyl end functional groups for Stille coupling reaction to further extend its conjugation and enable absorption into the near-infrared region.

In polymer organic solar cells, IDTB6-2Sn is used as an intermediate for more complicated structures such as low bandgap polymers or non-fullerene acceptors, such as IDT-2Br or IEICO-4F.

Part of our range of non-fullerene acceptor monomers, we stock high purity (>98%) IDTB6-2Sn for priority dispatch (lead times may apply for large quantities, please contact us for details). Qualifying orders ship free.

Enabling facile coupling reaction

With trimethylstannyl end groups

High purity

>98% IDTB6-2Sn Purity

Worldwide shipping

Quick and reliable shipping

Electron-rich building block

Preparation of low bandgap non-fullerene acceptors (NFAs)

General Information

CAS Number	1252555-61-5
Chemical Formula	C₇₀H₉₀S₂Sn₂
Molecular Weight	1233.03 g/mol
Full Name	4,4,9,9-tetrakis(4-hexylphenyl)-4,9-dihydro-s-indaceno[1,2-b:5,6-b']dithiophene-2,7-diyl)bis(trimethylstannane)
Synonyms	IDT-nC6 1,1'-[4,4,9,9-tetrakis(4-hexylphenyl)-4,9-dihydro-s-indaceno[1,2-b:5,6-b']dithiophene-2,7-diyl]bis[1,1,1-trimehtylstannyl]stannane
Classification / Family	Indaceno[1,2-b:5,6-b']dithiophene (IDT), Monomer and intermediates, None-fullerene acceptors (NFAs), NFA-OSCs, printing electronics

Chemical Structure

Product Details

Purity	>98% (by NMR)
Melting Point	N/A
Appearance	Yellow crystalline powder

MSDS Documentation

IDTB6-2Sn MSDS Sheet

Literature and Reviews

Indacenodithiophene-Based Wide Bandgap Copolymers for High Performance Single-Junction and Tandem Polymer Solar Cells. Y.Ma et al., Nano Energy, 33, 313-324 (2017); DOI: 10.1016/j.nanoen.2017.01.050.
A cyclopentadithiophene-bridged small molecule acceptor with near-infrared light absorption for efficient organic solar cells, Y. Yi et al, J. Mater. Chem. C, 7, 4013-4019 (2019); DOI: 10.1039/c9tc00162j.
Efficient Semitransparent Solar Cells with High NIR Responsiveness Enabled by a Small-Bandgap Electron Acceptor, F. Liu et al., 29 (21), 1606574 (2017); DOI: 10.1002/adma.201606574.

HOMO Energy Level Regulation of Novel Conjugated Copolymers for Polymer Solar Cells, J. Zhang et al., New J. Chem., 39, 6548-6554 (2015); DOI: 10.1039/C5NJ01105A.
Solution-processed, indacenodithiophene-based, small-molecule organic field-effect transistors and solar cells, D. Liu et al., J. Mater. Chem. C, 2, 7523 (2014); DOI: 10.1039/c4tc00721b.