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COOH Functionalized Multi-Walled Carbon Nanotubes

CAS Number 308068-56-6

Anode Materials, Battery Materials, Carbon Nanotubes (CNTs), Low Dimensional Materials


Product Code M2010D2-500mg
Price $137 ex. VAT

Carboxylated multi-walled carbon nanotubes (MWCNT-COOH)

as functionalized MWCNTs applied in a wide range of applications including solar cells, batteries and polymer reinforcement


Overview | Product Information | Related Products


COOH functionalized multi-walled carbon nanotubes (MWCNT-COOH) are multi-walled carbon nanotubes with carboxylic acid groups attached on the surface of the nanotubes. MWCNT-COOH can be prepared by reacting pristine MWCNTs with a mixture of HNO3:H2SO4 (1:3 volume ratio). Compared to pristine MWCNTs, COOH functionalized multi-walled carbon nanotubes provide better dispersibility in solvents and polymer resins. The homogeneous MWCNT-COOH composites reduce the mechanical defects, leading to improved tensile and compressive strength.

Other than improving the dispersity of MWCNTs in solution, carboxylic acid groups can interact with other materials. For example, MWCNT-COOH can form hydrogen bonds with poly(ethylene oxide) (PEO) in solid state lithium batteries. The intermolecular interaction reduces the crystallinity of PEO, improving the migration abilities of lithium ion. A lithium battery cell, containing MWCNT-COOH, exhibits a capacity of 150 mAh/g at 0.5 C-rate at 120 °C, and a capacity retention of nearly 100% after 100 charge and discharge cycles.

High Purity Multi-Walled Carbon Nanotubes

High Purity

>96% COOH functionalized MWCNTs

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Applications of Multi-Walled Carbon Nanotubes

Versatile Applications

Improve mechanical or electrical properties

General Information


CAS Number 308068-56-6
Chemical Formula CxHyOz
Full Name Carboxylated multi-walled carbon nanotubes
Recommended Dispersants DI water, DMF, THF, ethanol, and acetone
Synonyms Carboxylated multi-walled carbon nanotubes, COOH multi-walled carbon Nanotubes, Carboxylated-MWCNTs, COOH-MWCNTs
Classification or Family 1D materials, Carbon nanomaterials, Nanomaterials, Polycyclic aromatic hydrocarbons, thin-film electronics
Appearance Black fibrous powder

Chemical Structure


COOH functionalized multi-walled carbon nanotubes, MWCNT-COOH
COOH functionalized multi-walled carbon nanotubes, MWCNT-COOH, CAS number 308068-56-6

Product Details


Product Code M2010D2 M2010D3 M2010D4 M2010D5 M2010D6
Internal Diameter (nm) 5 – 10 5 – 12 5 – 15 2 – 6 5 – 10
External Diameter (nm) 25 40 > 50 < 8 8 – 18
Length (μm) 10 – 20 10 – 20 10 – 20 10 – 35 10 – 35
COOH Content (wt%) 0.6 0.4 0.3 3.7 2.2
Specific surface Area (m2/g) > 55 > 30 > 30 300 – 500 210
Purity (%) > 99.9% > 99.9% > 99.9% > 96% > 96%

MSDS Documentation


COOH functionalized multi-walled carbon nanotubesCOOH functionalized multi-walled carbon nanotubes MSDS sheet

References


  • Multi-walled carbon nanotubes as hole collectors in inverted perovskite solar cells, A. Elseman et al., ACS Appl. Nano Mater., 7 (8), 8792–8803 (2024); DOI: 10.1021/acsanm.4c00262.
  • Insights into selective removal by dye adsorption on hydrophobic vs multivalent hydrophilic functionalized MWCNTs, J. Arévalo-Fester et al., ACS Omega, 8, 11233–11250 (2023); DOI: 10.1021/acsomega.2c08203.
  • Insights into Li+ storage mechanisms, kinetics, and reversibility of defect-engineered and functionalized multi-walled carbon nanotubes for enhanced energy storage, L. Kong et al., J. Mater. Chem. A, 12, 4299 (2024); DOI: 10.1039/d3ta07362a.


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