PNDI(2HD)2T
CAS Number 1459168-70-7
Materials, OFET & OLED Polymer Materials, OPV Polymers, Semiconducting Polymers
PNDI(2HD)2T, polymer acceptor in high performance all-PSCs
High purity polymer available for fast, secure dispatch
Specifications | MSDS | Literature and Reviews
PNDI(2HD)2T, also known as P(NDI2HD-T2), CAS number 1459168-70-7, copolymer of naphthalene and bithiophene, is used as a polymer acceptor in high performance all-PSCs.
Compared to PNDI(2OD)2T, PNDI(2HD)2T exhibits a higher degree of crystalline behaviours. This facilitates superior 3D charge-transport between polymer donor and acceptor materials, resulting in enhanced device performance for all-PSCs. When PNDI-bithiophene copolymers with different side-chain length were compared, the maximum µe,FET value was identified as 0.39, 1.22 and 1.90 cm2 V−1 s−1 for PNDI(2DT)2T, PNDI(2OD)2T, and PNDI(2HD)2T respectively [2].
Luminosyn™ PNDI(2HD)2T
Luminosyn™ PNDI(2HD)2T is now available.
High molecular weight and high purity
PNDI(2HD)2T is purified via Soxhlet extraction with methanol, hexane and chlorobenzene under an argon atmosphere
Large quantity orders
Plan your experiments with confidence with polymers from the same batch
General Information
| Full name | Poly{[N,N'-bis(2-hexyldecyl)naphthalene-1,4,5,8-bis(dicarboximide)-2,6-diyl]-alt-5,5'-(2,2'-bithiophene)} |
| Synonyms |
|
| Chemical formula | (C54H72N2O4S2)n |
| CAS number | 1459168-70-7 |
| HOMO / LUMO | HOMO = -5.80 eV, LUMO = -3.82 eV [1] |
| Classification / Family | PNDI polymers, Organic n-type semiconducting materials, Organic photovoltaics, All-polymer solar cells (All-PSCs), Electron-acceptor polymers, OFETs, Perovskite solar cells. |
| Soluble in | Chloroform, chlorobenzene, dichlorobenzene |
| Recommended Processing Solvents at 10mg/ml | Dichlorobenzene or Chlorobenzene+dichlorobenzene (1:1 v/v) at elevated temperature ca. 60 °C |
Batch Details
| Batch number | MW | PDI | Stock info |
|---|---|---|---|
| M2082A3 | 143,634 | 1.93 | In stock |
Chemical Structure
MSDS Documentation
PNDI(2HD)2T MSDS sheetLiterature and Reviews
- Rationally Designed Donor–Acceptor Random Copolymers with Optimized Complementary Light Absorption for Highly Efficient All-Polymer Solar Cells, S. Kim et al., Adv. Funct. Mater., 27, 1703070 (2017); DOI: 10.1002/adfm.201703070.
- Side Chain Optimization of Naphthalenediimide–Bithiophene-Based Polymers to Enhance the Electron Mobility and the Performance in All-Polymer Solar Cells, W. Lee et al., Adv. Funct. Mater., 26, 1543–1553 (2016); DOI:10.1002/adfm.201504191.
- Controlling Molecular Orientation of Naphthalenediimide-Based Polymer Acceptors for High Performance All-Polymer Solar Cells, J. Jung et al., Adv. Energy Mater., 6 (15), 1600504 (2016), DOI:10.1002/aenm.201600504.