PNDI(2HD)T

CAS Number 1675973-74-6

Luminosyn™ Polymers, Materials, OFET & OLED Polymer Materials, OPV Polymers, Semiconducting Polymers

PNDI(2HD)T, polymer acceptor for high performance all-PSCs

High quality polymer available for fast, secure dispatch

Specifications | Pricing and Options | MSDS | Literature and Reviews

PNDI(2HD)T, CAS number 1675973-74-6, also known as P(NDI2HD-T), is a copolymer used as a polymer acceptor in high-performance all-polymer solar cells (All-PSCs).

All-PSCs based on PBDTTTPD and PNDI(2HD)T exhibited a PCE of 6.64% with better flexibility, stretching, and bending properties when compared to polymer solar cells with PCBMs as acceptors. The high performances of these devices with P(NDI2HD-T) as polymer acceptor was due to the high open circuit voltage (1.06 V) and favourable interfacial interactions between the active layers of polymer donor and acceptor.

It has also been demonstrated that a combination of polymer and small molecule acceptors, such as P(NDI2HD-T)/ITIC with only a small amount of ITIC in presence, significantly improves the device PCE from 6% to over 7% when PTP8 was used as polymer donor [5].

Luminosyn™ PNDI(2HD)T

Luminosyn™ PNDI(2HD)T (also referred to as P(NDI2HD-T)) is now available.

Higher molecular weights and high purity
PNDI(2HD)T is purified via Soxhlet extraction with methanol, hexane and chlorobenzene under an argon atmosphere

Batch-specific GPC data
Have confidence in what you are ordering; batch-specific GPC data for your thesis or publications

Large quantity orders
Plan your experiments with confidence with polymers from the same batch

General Information

Full name	Poly{[N,N'-bis(2-hexylldecyl)naphthalene-1,4,5,8-bis(dicarboximide)-2,6-diyl]-alt-2,5-thiophene}
Synonyms	P(NDI2HD-T) PNDI-T-HD Polynaphthalene diimide-thiophene
Chemical formula	(C₅₀H₇₀N₂O₄S)_n
CAS number	1675973-74-6
HOMO / LUMO	HOMO = -5.64 eV, LUMO = -3.79 eV [1]
Classification / Family	PNDI polymers, Organic n-type semiconducting materials, Organic photovoltaics, All-polymer solar cells (All-PSCs), Electron-acceptor polymers, OPV acceptors, OFETs, Perovskite solar cells.
Solubility	Soluble in chlorobenzene, dichlorobenzene

Chemical Structure

Chemical structure and product image of P(NDI2HD-T)

Pricing

Batch	Quantity	Price
M2081A	100 mg	£400
M2081A	250 mg	£800
M2081A	500 mg	£1450
M2081A	1 g	£2600

Batch details

Batch	M_w	M_n	PDI	Stock Info
M2081A1	267,653	148,132	1.81	Discontinued
M2081A2	193,704	105,414	1.84	In stock

MSDS Documentation

PNDI(2HD)T MSDS Sheet

Literature and Reviews

Flexible, highly efficient all-polymer solar cells, T. Kim et al., Nat. Commun., 6, 8547 (2015); DOI: 10.1038/ncomms9547.
Impact of highly crystalline, isoindigo-based small molecular additives for enhancing the performance of all-polymer solar cells, H-H. Cho et al., J. Mater. Chem. A, 5, 21291–21299 (2017); DOI: 10.1039/c7ta06939a.
Comparative Study of Thermal Stability, Morphology, and Performance of All-Polymer, Fullerene–Polymer, and Ternary Blend Solar Cells Based on the Same Polymer Donor, T. Kim et al., Macromolecules, 50 (17), 6861–6871 (2017);
DOI: 10.1021/acs.macromol.7b00834.

High-Performance All-Polymer Solar Cells Via Side-Chain Engineering of the Polymer Acceptor: The Importance of the Polymer Packing Structure and the Nanoscale Blend Morphology, C. Lee et al., Adv. Mater., 27, 2466–2471 (2015); DOI: 10.1002/adma.201405226.
High-performance all-polymer nonfullerene solar cells by employing an efficient polymer-small molecule acceptor alloy strategy, G Ding et al., Nano Energy, 36, 356-365 (2017); https://doi.org/10.1016/j.nanoen.2017.04.061