4',4''',4'''''-(1,3,5-triazine-2,4,6-triyl)tris([1,1'-biphenyl]-4-amine)

Covalent organic frameworks (COFs) Trazine ligand

Triangular amine bridging ligand for the synthesis of COFs in application of photocatalyst for hydrogen evolution reactions (HERs), photo-biocatalytic reactions, and hydrogen peroxide production

Specifications | MSDS | Literature and Reviews

4',4''',4'''''-(1,3,5-triazine-2,4,6-triyl)tris([1,1'-biphenyl]-4-amine) (TABPT) is a trigonal triazine derivative with [1,1'-biphenyl]-4-amine] groups at 2,4,6-positions.

COF C6-TRZ-TFP, prepared by solvothermal Schiff base polycondensation of 2-hydroxybenzene-1,3,5-tricarbaldehyde (TFP) and 4,4′,4′′-(1,3,5-triazine-2,4,6-triyl)tris[(1,1′-biphenyl)-4-amine], showed excellent hydrogen evolution reaction activity in electrochemical water splitting, with a very low overpotential of 200 mV and specific activity of 0.2831 mA cm⁻² together with high retention of catalytic activity after a long duration of electrocatalysis in 0.5 M aqueous H₂SO4.

COF-4, obtained from the condensation of tripodal amine 4,4′,4″-(1,3,5-triazine-2,4,6-triyl)tris(([1,1′-biphenyl]-4-amine)) and 2,4,6-triformylresorcinol with very suitable band gaps of 1.95 eV, shows a high-efficiency photo-biocatalytic activity for coenzyme nicotinamide adenine dinucleotide NADH photo regeneration and enhanced visible light-driven formic acid production at a rate of 226.3 μmol g^–1 in 90 min.

MOF and COF ligands

Triazine ligand for cross-linked COF networks

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High purity

>98% High purity

Facile reactions

Readily polycondensation cross-coupling reactions to form COF networks

Polycondensation of benzotrithiophene (BTT) and (1,3,5-triazine-2,4,6-triyl)tris([1,1´-biphenyl]-4-amine) affords crystalline, and porous imine-linked COF with a BET surface area of 1200 m² g⁻¹. Room temperature in-plane electrical conductivity of up to 10⁻⁴ S m⁻¹ is measured for the COF film.

π-electron-extended triazine-based covalent organic framework (TFP-TPTPh COF) with excellent crystallinity and a high surface area of 724 m² g⁻¹, demonstrates remarkable photocatalytic degradation rate of RhB dye molecules with an efficiency of 97.02% under ultraviolet–visible light irradiation. Also, TFP-TPTPh COF shows an excellent photocatalytic capacity for reducing water to generate H₂ with a hydrogen evolution rate (HER) of 2712 μmol g⁻¹ h⁻¹.

General Information

Chemical Structure

Product Details

MSDS Documentation

4',4''',4'''''-(1,3,5-triazine-2,4,6-triyl)tris([1,1'-biphenyl]-4-amine) MSDS Sheet

Literature and Reviews

1. Metal-Free Triazine-Based 2D Covalent Organic Framework for Efficient H2 Evolution by Electrochemical Water Splitting, S. Ruidas et al., ChemSusChem, 14 (22), 5057-5064 (2021); DOI: 10.1002/cssc.202101663.
   
2. Band Gap Engineering in Solvochromic 2D Covalent Organic Framework Photocatalysts for Visible Light-Driven Enhanced Solar Fuel Production from Carbon Dioxide, N. Singh et al., ACS Appl. Mater. Interfaces, 13 (12), 14122–14131 (2021); DOI: 10.1021/acsami.0c21117.
   
3. Oriented Thiophene-Extended Benzotrithiophene Covalent Organic Framework Thin Films: Directional Electrical Conductivity, L. Frey et al., Adv. Funct. Mater., 32 (47), 2205949 (2022); DOI: 10.1002/adfm.202205949.
   
4. Covalent organic frameworks for direct photosynthesis of hydrogen peroxide from water, air and sunlight, F. Liu et al., Nat. Commun., 14, 4344 (2023); DOI: 10.1038/s41467-023-40007-4.
   
5. π-Electron-Extended Triazine-Based Covalent Organic Framework as Photocatalyst for Organic Pollution Degradation and H2 Production from Water, J. Wang et al., Polymers, 15(7), 1685 (2023); DOI: 10.3390/polym15071685.