4,4',4''-(pyridine-2,4,6-triyl)tribenzaldehyde
CAS Number 2230887-26-8
Carbaldehyde Monomers, Chemistry Building Blocks, COF Ligands, Materials, Monomers, Porous Organic Frameworks
Covalent Organic Frameworks (COFs) Pyridyl Ligand
An aldehyde functionalised bridging ligand linker for COFs in application of carbon dioxide uptake and energy storage
Specifications | MSDS | Literature and Reviews
4,4',4''-(Pyridine-2,4,6-triyl)tribenzaldehyde (TBAPy), CAS number 2230887-26-8, is a triagonal ligand linker with an electron deficient pyridine core connecting three benzaldehydes at 2,4,6-positions. The aldehyde functional groups can form imines via condensation reaction with amines for constructing covalent organic frameworks (COFs).
Car-TPP-COF, obtained through the condensations of triangular node Car-3NH2 and the triangular linker 4,4',4''-(pyridine-2,4,6-triyl)tribenzaldehyde to form imine linkages, demonstrated high surface area of 721 m2 g−1 and high degrees of CO2 capture of 34 mg g−1 at 298 K.
MOF and COF ligands
Aldehyde ligand for cross-linked COF networks
Worldwide shipping
Quick and reliable shipping
High purity
>98% High purity
Facile reactions
Aldehyde possesses excellent reactivity
General Information
| CAS Number | 2230887-26-8 |
|---|---|
| Chemical Formula | C26H17NO3 |
| Full Name | 4,4',4''-(pyridine-2,4,6-triyl)tribenzaldehyde |
| Molecular Weight | 391.42 g/mol |
| Synonyms | TFPP, TPP-3CHO, 2,4,6-Tri(4-formylphenyl)pyridine |
| Classification / Family | Pyridines, COF ligands, Benzaldehydes |
Chemical Structure
Product Details
| Purity | >98% |
|---|---|
| Melting Point | N/A |
| Appearance | White to grey powder to fibres/crystals |
MSDS Documentation
4,4',4''-(Pyridine-2,4,6-triyl)tribenzaldehyde MSDS Sheet
Literature and Reviews
-
Strategic design of triphenylamine- and triphenyltriazine-based two-dimensional covalent organic frameworks for CO2 uptake and energy storage, A. EL-Mahdy et al., J. Mater. Chem. A, 6, 19532-19541 (2018); DOI: 10.1039/C8TA04781B.
-
Hollow Microspherical and Microtubular [3 + 3] Carbazole-Based Covalent Organic Frameworks and Their Gas and Energy Storage Applications, A. EL-Mahdy et al., ACS Appl. Mater. Interfaces, 11, 9343−9354 (2019); DOI: 10.1021/acsami.8b21867.
- Advances in porous organic polymers: syntheses, structures, and diverse applications, M. Mohamed et al., Mater. Adv., 3, 707-733 (2022); DOI: 10.1039/D1MA00771H.