TmPyPB

TmPyPB, ETL/HBL material for organic electronic devices

Blended with TCTA to fabricate high-efficiency blue PHOLEDs

With a low-lying HOMO, high triplet energy level, and electron-deficient pyridine groups, TmPyPB is widely used as an electron-transport layer and hole-blocking layer material in organic electronic devices (such as OLEDs, OPV and perovskite solar cells).

Blending with a hole-transporting material such as TCTA, TmPyPB has been used as a co-host material to fabricate high-efficiency blue PhOLEDs.

TmPyPB, 1,3,5-Tris(3-pyridyl-3-phenyl)benzene from Ossila was used in the high-impact paper (IF 30.85), Rivers of Light—Ternary Exciplex Blends for High Efficiency Solution-Processed Red Phosphorescent Organic Light Emitting Diodes, J. Saghaei, et al., Adv. Funct. Mater., 2108128 (2021); 10.1002/adfm.202108128.

General Information

Product Details

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials.

Chemical Structure

Device Structure(s)

Device structure	ITO/HAT-CN (10 nm)/TAPC (45 nm)/TCTA (10 nm)/Ir(MDQ)2(acac) (0.3 nm)/TmPyPb (40nm)/Liq (2 nm)/Al (120 nm) [1]
Colour	Red
Max. Current Efficiency	29.9 cd/A
Max. EQE	16.2%

Device structure	ITO/HAT-CN (10 nm)/TAPC (45 nm)/TCTA (10 nm)/Ir(ppy)2(acac) (0.3 nm)/TmPyPb (40nm)/Liq (2 nm)/Al (120 nm) [1]
Colour	Green
Max. Current Efficiency	79.5 cd/A
Max. EQE	21.1%

Device structure	ITO/HAT-CN (10 nm)/TAPC (45 nm)/TCTA (10 nm)/FIrpic (0.3 nm)/TmPyPb (40nm)/Liq (2 nm)/Al (120 nm) [1]
Colour	Blue
Max. Current Efficiency	39.0 cd/A
Max. EQE	17.6%

Device structure	ITO/PEDOT:PSS(40 nm)/m-MTDATA:Ir(Flpy-CF3)3 (40 nm)/TmPyPB(55 nm)/LiF(0.5 nm)/Al(100 nm) [2]
Colour	Yellow
Max. Current Efficiency	74.3 cd/A
Max. Power Efficiency	97.2 lm W−1
Max. EQE	25.2%

Device structure	ITO (70 nm)/HAT-CN (10 nm)/TAPC (50nm)//26DCzPPy:Ir(ppy)3 (7%, 10 nm)/TmPYMB (25 nm)/TmPYMB:Li (5%, 30 nm)/LiF(1 nm)/Al (100 nm) [3]
Colour	Green
Max. Current Efficiency	66.2 cd/A
Max. Power Efficiency	77.1 lm W−1
Max. EQE	19.7%

Device structure	ITO/TPDPES:TBPAH (20 nm)/3DTAPBP (30 nm)/4CzPBP:11 wt% FIrpic (10 nm)/TmPyPB (40 nm)/LiF (0.5 nm)/Al (100 nm) [4]
Colour	Blue
Max. Power Efficiency	42.0 lm W−1
EQE@100 cd/m2	22%

Device structure	(ITO)/MoO3 (3 nm)/TCTA (50 nm)/TCTA:TmPyPb:FIrpic (20 nm)/TmPyPb (30 nm)/LiF (1 nm)/Al (120 nm) [5]
Colour	Blue
Max. Power Efficiency	55.4 lm W−1
Max. EQE	20.4%

Device structure	ITO/MoO3(10 nm)/NPB (60 nm)/POBPmDPA*:FIr6(20 nm)/TmPyPB (35 nm)/LiF/Al [6]
Colour	Blue
Max. Current Efficiency	37.0 cd/A
Max. Power Efficiency	140 lm W−1
Max. EQE	17.9%

*For chemical structure information, please refer to the cited references

Pricing

MSDS Documentation

TmPyPB MSDS sheet

Literature and Reviews

1. Highly Efficient White Organic Light-Emitting Diodes with Ultrathin Emissive Layers and a Spacer-Free Structure, S. Wu et al., Sci. Reports 6, 25821 (2016); doi:10.1038/srep25821.
2. Solution-Processed Phosphorescent Organic LightEmitting Diodes with Ultralow Driving Voltage and Very High Power Efficiency, S. Wang et al., Sci. Report, 5:12487 (2015); DOI: 10.1038/srep12487.
3. Highly efficient green, blue, and white phosphorescent inverted organic light-emitting diodes by improving charge injection and balance, H. Lee et al., J. Mater. Chem. C, 5, 9911--9919 (2017); DOI: 10.1039/c7tc02795h.