TPA-DCPP
CAS Number 1803287-94-6
Dopant Materials, Green Dopant Materials, High Purity Sublimed Materials, Materials, OLED Materials, Semiconducting Molecules
Green Dopant Material with Triphenylamine (TPA) Pendants
High purity sublimed thermally activated delayed fluorescent (TADF) emitter for highly efficient OLEDs
TPA-DCPP (CAS number 1803287-94-6), namely 7,10-bis(4-(diphenylamino)phenyl)-2,3-dicyanopyrazino-phenanthrene is a V-shaped molecule consisting of triphenylamine (TPA) as the donor and 2,3-dicyanopyrazino phenanthrene (DCPP) as the acceptor units.
TPA-DCPP undergoes thermally activated delayed fluorescence (TADF) to emit in the deep red/near-IR region. Nondoped OLED with TPA-DCPP as active layer exhibits a maximum external quantum efficiency (EQE) of 2.1 %, whereas the doped device had an EQE of almost 10 %.
Enhaces external quantum efficiency of OLED
Increase from 2.1% to 10%
Worldwide shipping
Quick and reliable shipping
High purity sublimed material
>99%
Unique molecular confirmation
V- shape molecule
Sensor based on TPA-DCPP organic semiconductor onto Al2O3 substrate with Au interdigital electrodes exhibits favorable sensing response of 76.4 % and ppb-level detection ability under 98 % relative humidity, also exhibits good repeatability, selectivity, and 396 days of long-term stability to ammonia NH3.
General Information
| CAS number | 1803287-94-6 |
|---|---|
| Chemical formula | C54H34N6 |
| Molecular weight | 766.89 g/mol |
| Absorption* | λmax 308, 458 nm (in film) |
| Fluorescence | λem 810 nm (in DCM) |
| HOMO/LUMO | HOMO = 5.3 eV, LUMO = 3.52 eV |
| Synonyms | 7,10-Bis(4-(diphenylamino)phenyl)-2,3-dicyanopyrazino-phenanthrene |
| Classification / Family | Triarylamine derivatives, Deep red dopant, NIR TADF materials, Sublimed materials. |
Product Details
| Purity | Sublimed* >99% (HPLC) |
|---|---|
| Melting point | TGA: Td ≥ 508 oC (5% weight loss), Tg = 165 oC |
| Appearance | Deep red crystals/powder |
* Sublimation is a technique used to obtain ultra pure-grade chemicals, see sublimed materials for OLED devices.
Chemical Structure
Pricing
| Grade | Product Code | Quantity | Price |
|---|---|---|---|
| Sublimed (>99% purity) | M2418A1 | 100 mg | £210 |
| Sublimed (>99% purity) | M2418A1 | 250 mg | £420 |
| Sublimed (>99% purity) | M2418A1 | 500 mg | £670 |
| Sublimed (>99% purity) | M2418A1 | 1 g | £1080 |
MSDS Documentation
TPA-DCPP MSDS SheetLiterature and Reviews
-
Highly Efficient Near-Infrared Delayed Fluorescence Organic Light Emitting Diodes Using a Phenanthrene-Based Charge-Transfer Compound, S. Wang et al., Angew. Chem. Int. Ed., 54, 1–6 (2015); DOI: 10.1002/anie.201506687.
-
The recombination zone adjusted by the gradient doping of TPA-DCPP for efficient and stable deep red organic light emitting diodes, Q. Zhang et al., RSC Adv., 11, 24436-24442 (2021); DOI: 10.1039/D1RA01567B.
-
A TPA-DCPP organic semiconductor film-based room temperature NH3 sensor for insight into the sensing properties, J. He et al., Sens. Actuators B: Chem., 237, 128940 (2021); DOI: 10.1016/j.snb.2020.128940.