TPA-DCPP
CAS Number 1803287-94-6
Dopant Materials, High Purity Sublimed Materials, Materials, Semiconducting Molecules
Green Dopant Material with Triphenylamine (TPA) Pendants
High purity sublimed thermally activated delayed fluorescent (TADF) emitter for highly efficient OLEDs
TPA-DCPP (CAS number 1803287-94-6), namely 7,10-bis(4-(diphenylamino)phenyl)-2,3-dicyanopyrazino-phenanthrene is a V-shaped molecule consisting of triphenylamine (TPA) as the donor and 2,3-dicyanopyrazino phenanthrene (DCPP) as the acceptor units.
TPA-DCPP undergoes thermally activated delayed fluorescence (TADF) to emit in the deep red/near-IR region. Nondoped OLED with TPA-DCPP as active layer exhibits a maximum external quantum efficiency (EQE) of 2.1 %, whereas the doped device had an EQE of almost 10 %.
Enhaces external quantum efficiency of OLED
Increase from 2.1% to 10%
Worldwide shipping
Quick and reliable shipping
High purity sublimed material
>99%
Unique molecular confirmation
V- shape molecule
Sensor based on TPA-DCPP organic semiconductor onto Al2O3 substrate with Au interdigital electrodes exhibits favorable sensing response of 76.4 % and ppb-level detection ability under 98 % relative humidity, also exhibits good repeatability, selectivity, and 396 days of long-term stability to ammonia NH3.
General Information
| CAS number | 1803287-94-6 |
|---|---|
| Chemical formula | C54H34N6 |
| Molecular weight | 766.89 g/mol |
| Absorption* | λmax 308, 458 nm (in film) |
| Fluorescence | λem 810 nm (in DCM) |
| HOMO/LUMO | HOMO = 5.3 eV, LUMO = 3.52 eV |
| Synonyms | 7,10-Bis(4-(diphenylamino)phenyl)-2,3-dicyanopyrazino-phenanthrene |
| Classification / Family | Triarylamine derivatives, Deep red dopant, TADF materials, Sublimed materials. |
Product Details
| Purity | Sublimed* >99% (HPLC) |
|---|---|
| Melting point | TGA: Td ≥ 508 oC (5% weight loss), Tg = 165 oC |
| Appearance | Deep red crystals/powder |
* Sublimation is a technique used to obtain ultra pure-grade chemicals, see sublimed materials for OLED devices.
Chemical Structure
Pricing
| Grade | Product Code | Quantity | Price |
|---|---|---|---|
| Sublimed (>99% purity) | M2418A1 | 100 mg | £210 |
| Sublimed (>99% purity) | M2418A1 | 250 mg | £420 |
| Sublimed (>99% purity) | M2418A1 | 500 mg | £670 |
| Sublimed (>99% purity) | M2418A1 | 1 g | £1080 |
MSDS Documentation
TPA-DCPP MSDS SheetLiterature and Reviews
-
Highly Efficient Near-Infrared Delayed Fluorescence Organic Light Emitting Diodes Using a Phenanthrene-Based Charge-Transfer Compound, S. Wang et al., Angew. Chem. Int. Ed., 54, 1–6 (2015); DOI: 10.1002/anie.201506687.
-
The recombination zone adjusted by the gradient doping of TPA-DCPP for efficient and stable deep red organic light emitting diodes, Q. Zhang et al., RSC Adv., 11, 24436-24442 (2021); DOI: 10.1039/D1RA01567B.
-
A TPA-DCPP organic semiconductor film-based room temperature NH3 sensor for insight into the sensing properties, J. He et al., Sens. Actuators B: Chem., 237, 128940 (2021); DOI: 10.1016/j.snb.2020.128940.