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Product Code M2079A2-100mg
Price $364 ex. VAT

PFN-I, high quality active layer material for blue OLEDs

Used to improve extraction efficiencies in organic electronic devices


Overview | Specifications | MSDS | Pricing and Options | Literature and Reviews


PFN-I (CAS number 1687752-60-8) is the diiodide salt of PFN, and is a conjugated polymer electrolyte (CPE). It is commonly used as an electron-interface layer material in organic electronic devices (including OLED, OPV and perovskite solar cells) to improve extraction efficiency. PFN-I is also used as an active layer material for blue OLED devices.

It is believed that the device performance of polymer LEDs with bilayer cathodes (such as. PFN-I/Al), can be enhanced to levels comparable to (and even higher than) those obtained from using Ca or Ba cathodes [1].

Cathode interlayer molecule

Cathode interlayer molecule

For high efficient OPV applications

Improve extraction efficiency

Improve extraction efficiency

as a conjugated polyelectrolyte

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enhance the device performance of polymer LEDs

Enhance device performance

strong polar ionic pendant groups

Due to its strong polar ionic pendant groups, PFN-I is soluble in methanol and water.

EL Polymer Cathode Luminance (cd m -2) QE (%) LE (Cd A-1)
MEH-PPV Al 6 0.02 0.02
MEH-PPV Ba/Al 749 2.46 2.1
MEH-PPV PNF-I/Al 773 2.85 2.4

General Information


Full name Poly[9,​9-​dioctyl-​9',​9'-​bis[3-​(trimethylammonio)​propyl]​[2,​2'-​bi-​9H-​fluorene]​-​7,​7'-​diyl iodide
Synonyms PFN-iodide
Chemical formula (C54H76N2)n 2I
CAS number 1687752-60-8
Classification/Family Conjugated polymers, Polymer electrolyte, Polyfluorenes, Electron interface layer materials, OLED, OPV, Perovskite materials

Chemical Structure


pfn-i, pfn-iodide
Chemical structure of PFN-I

MSDS Documentation


PFN-I MSDSPFN-I MSDS sheet

Pricing


Batch Quantity Price
M2079A 100 mg £280
M2079A 250 mg £560
M2079A 500 mg £950

Batch information


Batch Mw Mn PDI Stock info
M2079A1 65 kDa 28.3 kDa 2.3 Discontinued
M2079A2 150 kDa 51.7 kDa 2.9 In Stock
M2079A3 62 kDa 34.4 kDa 1.8 Discontinued

Literature and References


  1. Efficient Electron Injection from a Bilayer Cathode Consisting of Aluminum and Alcohol-/Water-Soluble Conjugated Polymers, H. Wu et al., Adv. Mater., 16, 1826–1830 (2004), DOI: 10.1002/adma.200400067.
  2. Bimolecular Excited-State Electron Transfer with Surprisingly Long-Lived Radical Ions, A. A. Alsam et al., J. Phys. Chem. C 2015, 119, 21896−21903 (2015); DOI: 10.1021/acs.jpcc.5b06636.
  3. High-performance semi-transparent polymer solar cells possessing tandem structures, C. Chen et al., Energy. Environ. Sci., 6, 2714-2720( 2013); DOI: 10.1039/c3ee40860d.

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