2,3,6,7,10,11-Hexamethoxytriphenylene
CAS Number 808-57-1
Chemistry Building Blocks, COF Ligands, Liquid Crystals, Non-Heterocyclic Building Blocks, Optoelectronic Materials, Porous Organic Frameworks
A Fully Conjugated Triphenylene Ligand
As a disc-shaped planar molecule applied in liquid crystals, batteries, and macromolecules
Overview | Product Information | MSDS | Related Products
2,3,6,7,10,11-Hexamethoxytriphenylene (CAS number 808-57-1) is a D3h symmetric molecule functionalized with six methoxy groups at the ortho-positions. 2,3,6,7,10,11-Hexamethoxytriphenylene exhibits high reversibility in electrochemical redox reactions, enabling its application as a cathode material. The battery cell incorporating 40 wt% of 2,3,6,7,10,11-hexamethoxytriphenylene demonstrates full specific capacity at current densities up to 3 C. Being a planar molecule, 2,3,6,7,10,11-Hexamethoxytriphenylene finds its application in fundamental studies on charge-transfer interaction by scanning tunneling microscopy.
2,3,6,7,10,11-Hexamethoxytriphenylene can undergo demethylation with a strong Lewis acid for the synthesis of hexahydroxytriphenylene. Hexahydroxytriphenylene is used to prepare hydrogen-bonded frameworks, supported by its strong π–π interactions.
Triphenylene Building Block
Used in batteries, liquid crystals and porous organic frameworks
Conjugated Molecule
With a planar disc shape
High Purity
>98% pure
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General Information
| CAS Number | 808-57-1 |
|---|---|
| Chemical Formula | C24H24O6 |
| Full Name | 2,3,6,7,10,11-Hexamethoxytriphenylene |
| Molecular Weight | 408.44 g/mol |
| Synonyms | HMTP, HAT |
| Classification or Family | Porous organic frameworks, COFs, Batteries, Liquid crystals, Triphenylenes |
Chemical Structure
Product Details
| Purity | > 98% |
|---|---|
| Melting Point | N/A |
| Appearance | Brown powder |
MSDS Documentation
2,3,6,7,10,11-Hexamethoxytriphenylene MSDS Sheet
References
- 2,3,6,7,10,11-Hexahydroxytriphenylene tetrahydrate: a new form of an important starting material for supramolecular chemistry and covalent organic frameworks, F. Thébault et al., Acta Cryst. C67, 143–145 (2011); DOI: 10.1107/S0108270111002988.
- Rational synthesis of bis(hexyloxy)-tetra(hydroxy)-triphenylenes and their derivatives, M. Smith et al., RSC Adv., 4, 38281–38292 (2014); DOI: 10.1039/C4RA06503D.
- Self-assembly of a triphenylene-based-electron donor molecule on graphene: structural and electronic properties, J. Phys. Chem. C, 126, 9855–9861 (2022).
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