2',5'-Dimethoxy[1,1':4',1''-terphenyl]-4,4''-dicarboxylic acid
CAS Number 1392416-19-1
Chemistry Building Blocks, Materials, MOF Ligands, Porous Organic FrameworksMetal Organic Frameworks (MOFs) Terphenyl Ligand
A rigid linear ligand linker with flexible side functional groups for MOFs in applications of carbon dioxide storage and separation of CO2 and CH4.
Specifications | MSDS | Literature and Reviews
2′,5′-Dimethoxy-[1,1′:4′,1″-terphenyl]-4,4″-dicarboxylic acid (H2TPDC-OMe), a rigid terphenyl ligand with flexible functional groups, can provide various coordination modes and diverse architectures with inorganic metal cluster centres. With three linearly connected phenyl rings, 2′,5′-dimethoxy-[1,1′:4′,1″-terphenyl]-4,4″-dicarboxylic acid is also capable of showing photoluminescence.
Porous MOF [Cd(L)(OBA)]·DMF·H2O, where L is H2TPDC-OMe, shows high adsorption for CO2 with an uptake of 26.75 cm3/g at 295 K. {[Cd(L)(OBA)]·DMF·H2O}n also demonstrates great potential for selective separation of CO2 and CH4, due to the different interaction mechanism between the gases and the open metal sites.
General Information
CAS Number | 1392416-19-1 |
Chemical Formula | C22H18O6 |
Full Name | 2',5'-Dimethoxy[1,1':4',1''-terphenyl]-4,4''-dicarboxylic acid |
Molecular Weight | 378.37 g/mol |
Synonyms | H2TPDC-OMe |
Classification / Family | Terphenyl, MOF ligands, |
Chemical Structure
Product Details
Purity | >98% |
Melting Point | n.a. |
Appearance | White powder/crystal |
MSDS Documentation
2',5'-Dimethoxy[1,1':4',1''-terphenyl]-4,4''-dicarboxylic acid MSDS Sheet
Literature and Reviews
- Modulated Synthesis of Zr-Based Metal–Organic Frameworks: From Nano to Single Crystals, A. Schaate et al., Chem, Euro. J., 17 (24), 6643-6651 (2011); DOI: 10.1002/chem.201003211.
- Dysprosium-carboxylate nanomeshes with tunable cavity size and assembly motif through ionic interactions, B. Cirera et al., Chem. Commun., 52, 11227-11230 (2016); DOI: 10.1039/C6CC04874A.
- Enhanced water stability and high CO2 storage capacity of a Lewis basic sites-containing zirconium metal–organic framework, S. Demir et al., Dalton Trans., 50, 16587-16592 (2021); DOI: 10.1039/D1DT02772G.