4',4''',4'''''-Nitrilotris([1,1'-biphenyl]-3,5-dicarbaldehyde)
CAS Number 2030105-85-0
Carbaldehyde Monomers, Chemistry Building Blocks, COF Ligands, Monomers, Porous Organic Frameworks![4',4''',4'''''-Nitrilotris([1,1'-biphenyl]-3,5-dicarbaldehyde) MSDS](http://www.ossila.com/cdn/shop/t/305/assets/product-downloads-msds.svg?v=110835251789389989421733214861){kind=small}
![4',4''',4'''''-Nitrilotris([1,1'-biphenyl]-3,5-dicarbaldehyde) CAS 2030105-85-0](http://www.ossila.com/cdn/shop/files/tpa-6cho-chemical-structure-title.png?v=1721385802)
Covalent Organic Frameworks (COFs) Tri(biphenyl-4-yl)amine Ligand
functionalized with six aldehyde groups for highly cross-linked COFs with hierarchical porosity.
Overview | Product Information | Related Products
4',4''',4'''''-Nitrilotris([1,1'-biphenyl]-3,5-dicarbaldehyde) (TPA-6CHO, CAS number 2030105-85-0) is C3 symmetric COF ligand with a tri(biphenyl-4-yl)amine core. Each branch of TPA-6CHO has a double reaction site. With the combination of a C2 diamine ligand, TPA-6CHO forms heteropore-COFs. These heteropore-COFs contain with two types of hexagonal pores, exhibiting a hollow-spherical morphology.
TPA-6CHO is also used to construct zyg-type 3D COFs with amine derivatives with four reaction sites. The resulting COF stabilizes photoinduced donor-acceptor radical pairs in photocatalytic production of hydrogen peroxide. It shows a synthesis rate of hydrogen peroxide of 3324 μmol/g·h.
MOF and COF ligands
Tri(biphenyl-4-yl)amine ligand for cross-linked COF/MOF networks
Facile reactions
Aldehyde possesses excellent reactivity
High purity
>98% pure
Worldwide shipping
Quick and reliable shipping
General Information
| CAS Number | 2030105-85-0 |
|---|---|
| Chemical Formula | C42H27NO6 |
| Full Name | 4',4'',4'''-Nitrilotri(3,5-biphenyldicarbaldehyde) |
| Molecular Weight | 641.68 g/mol |
| Synonyms | 4'-[bis({3',5'-diformyl-[1,1'-biphenyl]-4-yl})amino]-[1,1'-biphenyl]-3,5-dicarbaldehyde, TPA-6CHO |
| Classification or Family | Porous organic frameworks, Carbaldehyde building block, COF ligands |
Chemical Structure
![4',4''',4'''''-Nitrilotris([1,1'-biphenyl]-3,5-dicarbaldehyde) chemical structure, CAS 2030105-85-0](https://www.ossila.com/cdn/shop/files/tpa-6cho-chemical-structure-body.png)
Product Details
| Purity | > 98% |
|---|---|
| Melting Point | N/A |
| Appearance | Bright yellow powder |
MSDS Documentation
![4',4''',4'''''-Nitrilotris([1,1'-biphenyl]-3,5-dicarbaldehyde) MSDS Sheet](https://www.ossila.com/cdn/shop/files/product-downloads-msds.svg){kind=small}
4',4''',4'''''-Nitrilotris([1,1'-biphenyl]-3,5-dicarbaldehyde) MSDS Sheet
References
- Photochromic radical states in 3D covalent organic frameworks with zyg topology for enhanced photocatalysis, T.-T. Ma et al., Natl. Sci. Rev., 11, 177 (2024); DOI: 10.1093/nsr/nwae177.
- Covalent organic frameworks: an ideal platform for designing ordered materials and advanced applications, Chem. Soc. Rev., 50, 120 (2021); DOI: 10.1039/d0cs00620c.
- Two-dimensional covalent organic frameworks with hierarchical porosity, Chem. Soc. Rev., 49, 3920 (2020); DOI: 10.1039/d0cs00049c.
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