((1,3,5-Triazine-2,4,6-triyl)tris(benzene-4,1-diyl))triboronic acid

CAS Number 910231-21-9

Boronates, Chemistry Building Blocks, COF Ligands, Materials, Porous Organic Frameworks

((1,3,5-Triazine-2,4,6-triyl)tris(benzene-4,1-diyl))triboronic acid MSDS

((1,3,5-Triazine-2,4,6-triyl)tris(benzene-4,1-diyl))triboronic acid CAS 910231-21-9

Covalent Organic Frameworks (COFs) Triazine Ligand

A trigonal boronic acid bridging ligand linker for covalent polymeric frameworks (CPFs) in application of sensors in the field of flexible and wearable electronics, and ciprofloxacin (CFX) detection

Overview
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((1,3,5-Triazine-2,4,6-triyl)tris(benzene-4,1-diyl))triboronic acid (TPBATRz), CAS number 910231-21-9, has a structure of triazine (Trz) core with three 4-phenylboronic acid anchoring groups attached at 1,3,5-positions. The boronic acid groups could help to extend the structure via Suzuki coupling reaction to form covalent polymeric frameworks (CPFs). The aromatic dendrimer structures bearing 2,4,6-triphenyl-1,3,5-triazine skeleton as the core features improved thermal stability and photophysical properties associated with improved electron-transfer processes toward the fabrication of OLEDs, OFETs and sensors.

Consisted of a triphenyltriazine core with three peripheral 3-hexylthiophene units, donor–acceptor (D–A) covalent polymeric framework CPF1 exhibited a fast switching time of 5.1 s for colouring and 8.6 s for bleaching with a high coloration efficiency of 163.7 cm² C⁻¹ and high optical contrast of 36% with a negligible loss of optical contrast over 150 cycles. Sensor based on CPF1 also exhibited high sensitivity, fast response time, and good stability for sensing pressure. The pressure sensor displayed an enhanced sensitivity of ∼2.92 kPa⁻¹ with the durability of ∼2500 cycles.

MOF and COF ligands

Boronic acid ligand for cross-linked COF networks

Worldwide shipping

Quick and reliable shipping

High purity

>98% High purity

Facile reactions

Readily for boronic acid condensation and Suzuki reaction

General Information

CAS Number	910231-21-9
Chemical Formula	C₂₁H₁₈B₃N₃O₆
Full Name	((1,3,5-Triazine-2,4,6-triyl)tris(benzene-4,1-diyl))triboronic acid
Molecular Weight	440.82 g/mol
Synonyms	TPBATRZ, TBBA, 2,4,6-tris(4'-dihydroxyborylphenyl)-1,3,5-triazine
Classification / Family	Triazines, Boronates, COF ligands

Chemical Structure

Product Details

Purity	> 98%
Melting Point	N/A
Appearance	White to off-white powder/crystals

MSDS Documentation

((1,3,5-Triazine-2,4,6-triyl)tris(benzene-4,1-diyl))triboronic acid MSDS Sheet

Literature and Reviews

Aromatic Dendrimers Bearing 2,4,6-Triphenyl-1,3,5-triazine Cores and Their Photocatalytic Performance, J. Cyniak et al., J. Org. Chem., 86, 6855−6862 (2021); DOI: 10.1021/acs.joc.1c00039.
Aggregation-induced electrochemiluminescence and molecularly imprinted polymer based sensor with Fe3O4@Pt nanoparticle amplification for ultrasensitive ciprofloxacin detection, S. Li et al., Microchem. J., 178, 107345 (2022); DOI: 10.1016/j.microc.2022.107345.
Vis-to-NIR electrochromism and bright-to-dark electrofluorochromism in a triazine and thiophene-based three-dimensional covalent polymer, S. Halder et al., Mol. Syst. Des. Eng., 7, 1658-1669 (2022); DOI: 10.1039/D2ME00119E.
Side-Chain Modification in Conjugated Polymer Frameworks for the Electrocatalytic Oxygen Evolution Reaction, N. Gupta et al., ACS Appl. Mater. Interfaces, 15 (24), 29042–29051 (2023); DOI: 10.1021/acsami.3c02726.
Piezoresistive pressure sensor based on conjugated polymer framework for pedometer and smart tactile glove applications, N. Gupta et al., Sens. Actuator A Phys., 350, 114139 (2023); DOI: 10.1016/j.sna.2022.114139.

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